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Exploring Magnesium-Aluminum Spinel Bricks: Composition and Exceptional High-Temperature Performance

2025-05-24
Sunrise
Technical knowledge
This article delves into the structural composition of magnesium-aluminum spinel bricks, primarily characterized by their main crystalline phase of forsterite and fundamental raw material of magnesium-aluminum spinel clinker. It highlights the superior qualities that arise from this composition, including excellent high-temperature shock resistance, elevated strength, and high-temperature volume stability, which are critical for various industrial applications that require materials to withstand extreme conditions.
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In high - temperature industries such as steelmaking, cement production, and non - ferrous metal smelting, refractory materials face a series of severe challenges. These challenges include high temperatures, chemical corrosion, and thermal shock, which can lead to rapid degradation of traditional refractory materials, affecting production efficiency and product quality. Magnesia - alumina spinel bricks have emerged as a solution to these problems, thanks to their unique composition and structure that endow them with outstanding high - temperature performance.

Composition and Microstructure

The main crystal phase of magnesia - alumina spinel bricks is periclase, and the basic raw material is magnesia - alumina spinel clinker. Periclase has high melting point and good chemical stability, which provides a solid foundation for the high - temperature performance of the bricks. The magnesia - alumina spinel phase has excellent thermal shock resistance and chemical resistance. Under the microscope, the microstructure of magnesia - alumina spinel bricks shows a well - developed crystal structure, where the periclase grains are closely packed, and the magnesia - alumina spinel phase fills the gaps between the periclase grains, forming a dense and stable structure.

Microstructure of magnesia - alumina spinel bricks

High - Temperature Performance Principles

Excellent High - Temperature Seismic Resistance

The magnesia - alumina spinel phase in the bricks can effectively absorb and disperse the stress generated by thermal shock. When the temperature changes rapidly, the spinel phase can deform to a certain extent without causing cracking of the bricks. Tests have shown that magnesia - alumina spinel bricks can withstand more than 20 thermal shock cycles from room temperature to 1200°C without significant damage, far exceeding the performance of many traditional refractory materials.

High Strength

The dense microstructure formed by the periclase and magnesia - alumina spinel phases gives the bricks high strength. At high temperatures, the mechanical properties of the bricks remain stable. For example, at 1000°C, the compressive strength of magnesia - alumina spinel bricks can reach more than 50 MPa, ensuring that the bricks can maintain their shape and structure under heavy loads in high - temperature environments.

High - Temperature Volume Stability

Both periclase and magnesia - alumina spinel have low thermal expansion coefficients. This means that during the heating and cooling process, the volume change of the bricks is very small. The linear expansion rate of magnesia - alumina spinel bricks from room temperature to 1500°C is less than 1%, which helps to prevent cracking and spalling of the bricks caused by volume changes.

High Refractoriness and Corrosion Resistance

The high melting point of periclase and the chemical stability of magnesia - alumina spinel make the bricks have a high refractoriness, generally above 1800°C. In addition, the bricks have strong resistance to various chemical substances, such as slag, molten metals, and alkaline gases. In the steelmaking process, magnesia - alumina spinel bricks can resist the corrosion of high - temperature slag for a long time, greatly extending the service life of the refractory lining.

Synergistic Mechanism of Characteristics

The various excellent characteristics of magnesia - alumina spinel bricks do not work independently but interact synergistically. For example, the high - temperature volume stability ensures that the bricks do not crack during the thermal shock process, which is beneficial to the performance of high - temperature seismic resistance. The high strength and corrosion resistance work together to ensure that the bricks can maintain their integrity and functionality in harsh high - temperature and corrosive environments.

Practical Application Cases

In a large - scale steelmaking plant, the use of magnesia - alumina spinel bricks in the converter lining has extended the lining's service life from 1000 heats to more than 2000 heats. In a cement rotary kiln, the application of magnesia - alumina spinel bricks has reduced the frequency of refractory material replacement, improving the production efficiency of the kiln by more than 15%.

Magnesia - alumina spinel bricks in a cement rotary kiln

If you are looking for a refractory material that can be stably used in high - temperature environments, magnesia - alumina spinel bricks will be your ideal choice. These bricks offer a combination of high - temperature resistance, strength, and corrosion resistance that can significantly improve the efficiency and longevity of your industrial processes. Don't miss out on this opportunity to enhance your operations. Contact us now to learn more about our magnesia - alumina spinel bricks and how they can benefit your business.

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